Beyond Born-Oppenheimer:Electronic Nonadiabatic Coupling Terms and Conical Intersections

奥本海默之外:非绝热电子耦合相与圆椎相交

物理化学

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发货周期:预计3-5周发货
作      者
出  版 社
出版时间
2006年04月05日
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ISBN
9780471778912
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页      码
234
语      种
英文
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INTRODUCING A POWERFUL APPROACH TO DEVELOPING RELIABLE QUANTUM MECHANICAL TREATMENTS OF A LARGE VARIETY OF PROCESSES IN MOLECULAR SYSTEMS. The Born-Oppenheimer approximation has been fundamental to calculation in molecular spectroscopy and molecular dynamics since the early days of quantum mechanics. This is despite well-established fact that it is often not valid due to conical intersections that give rise to strong nonadiabatic effects caused by singular nonadiabatic coupling terms (NACTs). In Beyond Born-Oppenheimer, Michae
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