Topological Polymer Chemistry

图书简介

This book provides a comprehensive description of topological polymers, an emerging research area in polymer science and polymer materials engineering. The precision polymer topology designing is critical to realizing the unique polymer properties and functions leading to their eventual applications. The prominent contributors are led by Principal Editor Yasuyuki Tezuka and Co-Editor Tetsuo Deguchi. Important ongoing achievements and anticipated breakthroughs in topological polymers are presented with an emphasis on the spectacular diversification of polymer constructions. The book serves readers collectively to acquire comprehensive insights over exciting innovations ongoing in topological polymer chemistry, encompassing topological geometry analysis, classification, physical characterization by simulation and the eventual chemical syntheses, with the supplementary focus on the polymer folding, invoked with the ongoing breakthrough of the precision AI prediction of protein folding. The current revolutionary developments in synthetic approaches specifically for single cyclic (ring) polymers and the topology-directed properties/functions uncovered thereby are outlined as a showcase example. This book is especially beneficial to academic personnel in universities and to researchers working in relevant institutions and companies. Although the level of the book is advanced, it can serve as a good reference book for graduate students and postdocs as a source of valuable knowledge of cutting-edge topics and progress in polymer chemistry.

Part I: Introduction.- 1. Polymers meet topology.- Part II: Fundamentals of topological polymers.- 2. Classification and notation by graph theory.- 3. Statistic physics and computational analyses.- Part III: Synthetic chemistry of topological polymers.- 4. Electrostatic self-assembly and covalent fixation (ESA-CF).- 5. Synthesis of spiro-polycyclic topological polymers.- 6. Synthesis of bridged-polycyclic topological polymers.- 7. Synthesis of fused-polycyclic topological polymers.- 8. Synthesis of hybrid-polycyclic topological polymers.- Part IV: Topological polymer chemistry of macromoleclar chain folding.- Chapter 9. Programmed folding of linear polymers.- 10. Cyclic polypeptide (Cyclotide) by chain folding.- 11. Chemical construction of a K3,3 graph polymer topology.- Part V: Topological polymer chemistry of macromolecular networks.- 12. Topological polymer chemistry of macromolecular networks.- Part VI: Topological polymer chemistry of macromolecular knots and catenanes.- 13. Knots and links by DNAs and proteins.- 14. Chemical synthesis of macromolecular knots and catenanes.- Part VII: Innovations with cyclic polymers: Syntheses.- 15. Ring-closure of polymer precursors (RC).- 16. Ring-expansion of cycloalkenes and alkynes by transition metal catalysts (RE).- 17. Ring-expansion of heterocyclic and vinyl monomers by zwitterionic propagation (RE).- 18. Electrostatic self-assembly and covalent fixation (ESA-CF).- Part VIII: Innovations with cyclic polymers: Topology effects.- 19. Computational and experimental analyses in solution and bulk states.- 20. Dynamic properties and response behaviors.- 21. Amplifying topology effects by self-assemblies.- 22. Transforming cyclic/linear polymer topologies.- 23. Advanced applications of tailored cyclic polymers.- Part IX: Conclusion.- 24. Ongoing innovations and future perspectives.

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Topological Polymer Chemistry 拓扑聚合物化学：概念与实践 化学史

Topological Polymer Chemistry

拓扑聚合物化学：概念与实践
化学史