图书简介
This book reviews recent experimental and theoretical evidence that the physical and structural properties of transition metal oxides may decisively be influenced by strong spin-orbit interactions that compete with comparable Coulomb, magnetic exchange, and crystalline electric field interactions.
Preface; I. Fundamental Principles; 1 Introduction; 1.1. Overview; 1.2. Outline of the Book; 1.3. Fundamental Characteristics of 4d- and 5d-Transition Metal Oxides; 1.4. Crystal Fields and Chemical Aspects; 1.5. Electron-Lattice Coupling; 1.6. Spin-Orbit Interactions; 1.7. The Dzyaloshinsky-Moriya Interaction; 1.8. Phase Diagram of Correlated, Spin-Orbit-Coupled Matter; 1.9. Absence of Topological States in 4d- and 5d-Transition Metal Oxides; Further Reading; References; II. Phenomena in 4d- and 5d-Transition Metal Oxides; 2 Spin-Orbit Interactions in Ruddlesden-Popper Phases Srn 1IrnO3n 1 (n = 1, 2 and ?); 2.1. Overview; 2.2. Novel Mott Insulator: Sr2IrO4; 2.3. Borderline Insulator: Sr3Ir2O7; 2.4. Metallic SrIrO3 and its Derivatives; Further Reading; References; 3 Magnetic Frustration; 3.1. Overview; 3.2. Two-Dimensional Honeycomb Lattices: Na2IrO3 and Li2IrO3; 3.3. Ruthenate Honeycomb Lattices: Na2RuO3 and Li2RuO3; 3.4. Three-Dimensional Honeycomb Lattices: b-Li2IrO3 and g-Li2IrO3 and Hyperkagome Na4Ir3O8; 3.5. Pyrochlore Iridates; 3.6. Double-Perovskite Iridates with Ir5 (5d4) Ions: Absence of Nonmagnetic Singlet Jeff = 0 State; 3.7. Quantum Liquid in Unfrustrated Lattice Ba4Ir3O10; Further Reading; References; 4 Lattice-Driven Ruthenates; 4.1 Overview; 4.2. Orbital and Magnetic Order in Doped Ca2RuO4; 4.3. Unconventional Magneto-Transport Properties of Ca3Ru2O7; 4.4. Pressure-Induced Transition from Interlayer Ferromagnetism to Intralayer Antiferromagnetism in Sr4Ru3O10; 4.5. General Remarks; Further Reading; References; 5 Electric-Current-Control via Strong Spin-Orbit-Coupling; 5.1. Overview; 5.2. Ca2RuO4; 5.3. Sr2IrO4; 5.4. General Remarks; Further Reading; References; III. Materials Synthesis; 6 Single-Crystal Synthesis; 6.1. Overview; 6.2. Flux Technique; 6.3. Optical Floating-Zone Technique; 6.4. Field-Altering Technology; Further Reading; References; Appendix: Synopses of Selected Experimental Techniques; Subject Index; Compound Index
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