图书简介

1. Introduction./ 2. General Kinetic Rules for Chemical Reactions, Collisional, and Intramolecular Processes./ 2.1. Rates of Reaction, Collisional, and Spontaneous Processes. Rate Constant. Kinetic Types of Simple Processes./ 2.2. Chemical Equilibrium. Equilibrium Constant./ 2.3. Arrhenius equation./ 2.4. Complex Reactions./ 2.4.1. Consecutive Reactions. Steady/state Method./ Problems./ References./ 3. Theory of Elementary Processes./ 3.1. Cross/sections, Rate Constants, and Probabilities of Elementary processes./ 3.2. The detailed balance principle. Adiabatic approximations. Potential Energy Curves and Surfaces./ 3.3. Descriptions of Collisional Processes using Potential Energy Curves and Surfaces. Intramolecular Vibrational Relaxation in Polyatomic Molecules./ 3.4. Non/adiabatic Transitions. Perturbation theory. Probabilities of Adiabatic and Non/adiabatic Transitions./ 3.5. Intermolecular Interactions. Types of Intermolecular Interactions./ 3.6. Semiempirical Model Potentials./ Problems./ References./ 4. Photoprocesses./ 4.1. Primary and Secondary Gas/Phase Photoprocesses. Quantum Yields of the Gas/Phase Photoprocesses./ 4.2. Optical Transitions. Selection Rules for Optical Transitions. Spin/Orbit Coupling and Spin/Forbidden Radiative Transitions./ 4.3. Absorption. Absorption Band Intensities. Einstein Transition Probabilities. Oscillator Strength. Transition Dipole Moment. Beer/Lambert Law./ 4.4. Franck/Condon Principle for Bound/bound and Bound/free Optical Transitions./ 4.5. Luminescence. Radiative lifetime. The Relationship between Einstein Transition Probabilities and Transition Dipole Moment./ 4.6. Intramolecular Perturbations. Selection Rules and Franck/Condon Principle for Intramolecular Perturbation. Perturbations between Bound States. Abnormally long Radiative Lifetime./ 4.7. Spontaneous Predissociation of Two/, Tri/ and Polyatomic Molecules. Classes of Predissociation Processes./ 4.8. Photodecay of Two/, Tri/ and Polyatomic Molecules. Long/lived States of Polyatomic Molecules./ References./ 5. Energy Transfer in Collisions./ 5.1. Translational/Translational Energy Transfer (T/T exchange)./ 5.2. Rotational/Translational Energy Transfer (R/T exchange)./ 5.3. Vibrational Energy Transfer (V/T, V/R,T Processes)./ 5.4. Non/adiabatic Coupling and Vibrational Energy Transfer./ 5.5. Collision/Induced Non/Adiabatic Transitions./ 5.6. Collision/Induced Predissociation./ 5.7. Vibrational Relaxation via Several Electronic States./ 5.8. Electronic Deactivation./ Problems./ References./ 6. Weakly/Bound Complexes./ 6.1. Hydrogen/ and Halogen/Bond Complexes./ 6.2. Van der Waals Complexes. 6.3. Rare gas/halogen Molecule Clusters./ References./ 7. Termolecular reactions./ 7.1. Termolecular recombination. Mechanism of Termolecular Recombination./ References./ 8. Chemiluminescence./ 8.1. Classes of Chemiluminescence Processes.Gas/P Rate Constants./ 8.2. General Rules of Radiative Recombination./ References./ Solution of Problems./ Index.

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