State-to-State Dynamical Research in the F+H2 Reaction System(Springer Theses)

F+H2 反应体系的状态对状态动力学研究(丛书)

原子核物理学

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作      者
Ren
出  版 社
出版时间
2013年11月22日
装      帧
平装
ISBN
9783642397554
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页      码
77
语      种
英文
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图书简介
This thesis addresses two important and also challenging issues in the research of chemical reaction dynamics of F+H2 system. One is to probe the reaction resonance and the other is to determine the extent of the breakdown of the Born-Oppenheimer approximation (BOA) experimentally. The author introduces a state-of-the-art crossed molecular beam-scattering apparatus using a hydrogen atom Rydberg ’tagging’ time-of-flight method, and presents thorough state-to-state experimental studies to address the above issues. The author also describes the observation of the Feshbach resonance in the F+H2 reaction, a precise measurement of the differential cross section in the F+HD reaction, and validation of a new accurate potential energy surface with spectroscopic accuracy. Moreover, the author determines the reactivity ratio between the ground state F(2P3/2) and the excited state F*(2P1/2) in the F+D2 reaction, and exploits the breakdown of BOA in the low collision energy.
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