图书简介
Written by a "who is who" of leading organic chemists, this anniversary volume represent the Organic Reactions editors’ choice of the most important, ground-breaking and versatile reactions in current organic synthesis. The 15 reaction types selected for this volume include reactions for carbon-carbon bond formation, cross-coupling reactions, hydro- and halofunctionalizations, among many others. In line with the successful recipe of the series, each chapter is focused on a single reaction, discussing its mechanism and stereochemistry, scope and limitations, applications to synthesis, comparison with other methods, and experimental procedures. Each chapter concludes with a tabular survey of selected key application examples, complete with reported reaction conditions and yields, to serve as a quick reference guide for synthesis planning.
1. The Negishi Cross-Coupling Reaction 1 Colin Diner and Michael G. Organ 2. Generation and Trapping of Functionalized Aryl- and Heteroarylmagnesium and -Zinc Compounds 63 Ferdinand H. Lutter, Maximilian S. Hofmayer, Jeffrey M. Hammann, Vladimir Malakhov, and Paul Knochel 3. Copper-Catalyzed, Enantioselective Hydrofunctionalization of Alkenes 121 Haoxuan Wang and Stephen L. Buchwald 4. The Catalytic, Enantioselective Favorskii Reaction: in Situ Formation of Metal Alkynylides and Their Additions to Aldehydes 207 Yeshua Sempere and Erick M. Carreira 5. Enantioselective Lithiation-Substitution of Nitrogen-Containing Heterocycles 255 Kevin Kasten, Nico Seling, and Peter O’Brien 6. Catalytic, Enantioselective, Transfer Hydrogenation 329 Masahiro Yoshimura and Masato Kitamura 7. Hydrofunctionalization of Alkenes by Hydrogen-Atom Transfer 383 Ryan A. Shenvi, Jeishla L. M. Matos, and Samantha A. Green 8. Carbon-Carbon Bond Formation by Metallaphotoredox Catalysis 471 Eric D. Nacsa and David W. C. MacMillan 9. Suzuki-Miyaura Cross-Coupling 547 Alexander B. Pagett and Guy C. Lloyd-Jones 10. ortho-Directed C-H Alkylation of Substituted Benzenes 621 Yusuke Ano and Naoto Chatani 11. Catalytic, Enantioselective, C-H Functionalization to Form Carbon-Carbon Bonds 671 Qing-Feng Wu, Gang Chen, Jian He, and Jin-Quan Yu 12. Catalytic, Enantioselective Fluorination Reactions 749 Richard T. Thornbury and F. Dean Toste 13. Catalyst-Controlled Glycosylation 801 Samuel M. Levi and Eric N. Jacobsen 14. Palladium-Catalyzed Amination of Aryl Halides 853 John F. Hartwig, Kevin H. Shaughnessy, Shashank Shekhar, and Rebecca A. Green 15. Catalytic, Enantioselective, Copper-Boryl Additions to Alkenes 959 Amir H. Hoveyda, Ming Joo Koh, Kyunga Lee, and Jaehee Lee Cumulative Chapter Titles by Volume 1057 Author Index, Volumes 1-100 1075 Chapter and Topic Index, Volumes 1-100 1083
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